I thought Hart was all bravado and no tactics. For instance, standing down the middle for the first one would have made the remaining four players think twice about keeping it straight. I'm convinced Derren Brown could help here.
I agree - don't dive early for one of the first two. Or if you are clever dive early for those and feign to dive for third against a player who has the ability to try the cheeky one. It's called using your noddle which Hart didn't. What was clever of Hart was saying he had studied every Italian players penalties - mind you it wa sonly clever if he was lying to make them think, a waste of time if he actually did it. Derren Brown may help, it requires luck but not totally a lottery when you go the pens
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http://www.metacafe.com/watch/2422803/derren_brown_football/